Cationbased resistive memory emerging nonvolatile memory technologies symposium san francisco bay area nanotechnology council april 6, 2012 michael n. An auzno filmaldoped zno device fabricated in this work exhibited no resistive switching rs. Design and analysis of future memories based on switchable resistive elements. Resistive switching random access memories rram with simple metalinsulatormetal stacks are under intensive investigation owing to their great promise for use in nextgeneration memory applications 15. In unipolar rram, the switching direction does not depend on the polarity of the applied voltage. He has authored six book chapters, more than 200 papers published in international journals and presented at international conferences, and four patents to his name. Rram is a type of nvm that uses a materials that changes the resistance when a voltage is applied.
Advances in resistive switching based memory devices. The three main classes are based on an electrochemical metallization mechanism, a valence change mechanism, and a thermochemical mechanism, respectively. However, their nonuniformity in switching, low yield, and unclear switching mechanism hinder their practical realization. In this work, we present symmetric metalinsulatormetal bipolar memristors based on roomtemperature deposition of charged titaniumoxide nanoparticles formed in vacuum by a physical process. Nonpolar resistive memory switching with all four possible.
A system in its highresistance state off is switched set by a threshold voltage into the lowresistance state on as sketched in fig. This report does not include patents related to resistive switching such as phase change random access memories and magnetic random access memories, but also ferroelectric random access memories. The value of v reset63% is roughly independent of r on while i reset63% increases with 1 r on. They combine the advantages of flash and dram dynamic random access memories while avoiding their drawbacks, and they might be. They all exhibit a distinctive fingerprint characterized by a pinched hysteresis loop confined to the first and the third quadrants of the v i plane whose contour shape in general changes with both the amplitude and frequency of any. The author explains the physics of the devices and provides a concrete description of the materials involved as well as the fundamental. Highperformance hfoxaloybased resistive switching memory crosspoint array fabricated by atomic layer deposition. The physical mechanism of resistive switching is generally attributed to the conductive filament made up of oxygen vacancies formation and rupture in the oxide due to field assisted oxygen ion migration. This brief describes how nonvolatile change of the resistance, due to the application of electric voltage allows for fabrication of novel digital memory devices. Resistive memories should not necessarily be made completely from new.
Resistive switching random access memory materials. In this letter, we present the characterization and modeling of the reset statistics of ptniow resistive random access memories. Resistive switching memory integrated with amorphous. Reset statistics of niobased resistive switching memories. Among the emerging memories, resistive switching memory rram raises strong interest due to its high speed, high density as a result of its simple twoterminal structure, and low cost of fabrication. The memory effect is based on resistive switching mechanisms that can be explained through the creation and destruction of conductive filaments in devices with metalinsulatormetal mim. Resistive switching random access memory materials, device, interconnects, and scaling considerations. We report on the conduction mechanisms of novel rumgocu and rumgota resistive switching memory rsm devices. A solutionprocessed, chitosanbased resistiveswitching memory device is demonstrated with ptagdoped chitosanag structure. Nanoionicsbased resistive switching memories nature. The customized approach exploits logic representations to synthesize for. Switching is called unipolar or symmetric when the switching procedure does not depend on the polarity of the voltage and current signal. Pdf resistive switching memories based on metal oxides. Voltagetime dilemma of pure electronic mechanisms in resistive.
All 2terminal nonvolatile memory devices based on resistance switching are memristors, regardless of the device material and physical operating mechanisms. They combine the advantages of flash and dram dynamic random access memories while avoiding their drawbacks, and they might be highly scalable. One step row readout technique and sensing circuitry mohammed e fouda, ahmed m. We confirmed that conductive filaments including a quantum point contact qpc in pt niopt rs cells were formed by semiforming, the first step of the forming process.
Yet, forgetfulness is not always a disadvantage since it releases memory storage for more important or more frequently accessed pieces of information and is thought to be necessary for individuals to. Highperformance hfoxaloybased resistive switching memory. This paper studies inmemory computing from two perspectives, i. Resistive switching memory based on bioinspired natural. Resistance switching memories are memristors 767 fig. We fabricated cu 2 obased nanoscale memory devices using 250nm viahole structures on silicon wafers.
Publishers pdf, also known as version of record includes final page. A resistive switching memory device consisting of reduced graphene oxide and indium tin oxide as topbottom two electrodes, separated by dielectric mos 2 nanosphere assemblies as the active interlayer, was fabricated. Inmemory computing with resistive switching devices. Logic synthesis for inmemory computing using resistive. Resistive switching memory and reconfigurable devices.
Combined with the inherent scalability of the resistive switching memory rram, where the switching region consists of a conductive filament as small as a single atom, nws may provide an ideal approach to reduce the device area to a range not accessible to conventional lithography. Shortterm memory to longterm memory transition in a. As it can be seen, the device switches from hrs to lrs at a high voltage v set. A, while few switching cycles are observed for wtao x. Polymerbased resistive memories good scalability, flexibility, low cost, ease of processing, 3dstacking. Organic resistive memory university of nebraskalincoln. Subsequently, the system returns to hrs at a voltage v reset lower than v set. Indepth understanding of resistive switching mechanism. Nanoionicsbased resistive switching memories request pdf. We also include in this report patent related to memristor. The memory device shows reproducible and reliable bipolar resistive switching characteristics. Sorry, we are unable to provide the full text but you may find it at the following locations. Advances in resistive switching memories based on graphene. This paper addresses the two main resistive switching rs memory technologies.
Resistive switching memory and reconfigurable devices by jiantao zhou a dissertation submitted in partial fulfillment of the requirements for the degree of doctor of philosophy electrical engineering in the university of michigan 2016 doctoral committee. Characterisation of novel resistive switching memory devices. Recent progress in resistive switching memories yoshio nishi stanford university stanford, california u. Overcoming the voltagetime dilemma of electrochemical metallization memories. Nanoionicsbased resistive switching memories dante r. Eltawil, senior member, ieee, and fadi kurdahi, fellow, ieee abstracttransistorbased memories are rapidly approaching their maximum density per unit area. Silicon compatible snbased resistive switching memory nanoscale. Resistive crossbar arrays enable denser memory due to the small size of switching. Many metalinsulatormetal systems show electrically induced resistive switching effects and have therefore been proposed as the basis for future nonvolatile memories. Conduction mechanisms on high retention annealed mgobased. This device exhibits the rewritable nonvolatile resistive switching with low setreset voltage. Pdf resistive switching memory based on bioinspired. The resistive switching in such memory device is attributed to electron transfer reaction between reduced graphene oxide sheets and thionine molecules.
Unlike modern semiconductor memory devices, needless to say, human memory is by no means eternal. A novel resistive random access memory device is designed with srtio3 la23srmno3 lsmomgal2o4 maocu structure, in which metallic epitaxial lsmo is employed as the bottom electrode rather. They are subdivided into cationmigration cells, based on the electrochemical growth and dissolution of metallic filaments, and anionmigration cells, typically realized with transition metal oxides as the insulator, in which electronically conducting paths of suboxides are formed and removed. A memory device based on natural organic material is a promising device toward the next generation of nonvolatile nanoelectronics. His research group investigates emerging device technologies, such as phase change memory pcm and resistive switching memory reram for both memory and computing applications. Yet another class of resistive switching phenomena is based on the electrically stimulated change of the resistance of a metalinsulator metal mim memory cell.
The resistance switching behaviour of several materials has recently attracted considerable attention for its application in nonvolatile memory nvm devices, popularly described as resistive random access memories rrams. Lowenergy resistive random access memory devices with no. One of the first reported polymer based resistive switching memory. Organic resistive memory polymers, organic smallmolecule compounds, and inorganicorganic hybrid yuewei yin xus group meeting 02122016. In this thesis, a defect probing technique based on the random telegraph noise rtn is developed for both filamentary and nonfilamentary devices, which can reveal the resistive switching mechanism at defect level and can also. The cu 2 o as the resistive switching layer of nanoscale memory devices was deposited using ecd.
Large banks of cheap, fast, nonvolatile, energy efficient, scalable solidstate memories are an increasingly essential component for todays data intensive. One of the most striking features of these devices is that they do not require a forming step, which is to be related to protrusions of the top electrode material inside the intrinsically porous. Uses polysilicon fuses to connect the emitter of each bjt to the digital marx capital 1 pdf line. The electrical switching behaviors of some polymer materials have been. Nonvolatile resistive switching memoriescharacteristics. Enhanced resistive switching memory characteristics and. The carrier screening effect occurs commonly in dielectric materials. The device shows nonvolatile resistive switching behaviors with an onoff ratio of more than 10 4, fast switching speed of 10 5 s, and good endurance. However, details of the underlying microscopic behaviour of the resistive switching in rram are still largely missing. Appearance of quantum point contact in ptniopt resistive. Memories in digital electronics pdf 5 digital circuitry page 1 of 21.
Integration scheme of nanoscale resistive switching memory. In the following, an overv research work on conductivebridge memory metal oxide resistive switching memory oxr a reram cell is generally built by a cap insulatormetal mim structure, composed resistive material i sandwiched betwe conductors m as illustrated in fig. Resistive switching memories in mos2 nanosphere assemblies. Memory is an essential building block in learning and decisionmaking in biological systems. However, the tao x based rram devices with prospective and challenges. Resistance switching memories are memristors springerlink. As a model system for device physics study, hfox based rram devices were fabricated and characterized. Redoxbased resistive random access memory, or reram, is an emerging class of nanoelectronics elements which tend to rely upon filamentary behavior in order to realize multistate switching. Resistive switching in polymer technische universiteit eindhoven. In the area of materials, resistive hysteretic switching bistable or multilevel switching has got a great attention. They all exhibit a distinctive fingerprint characterized by a pinched hysteresis loop confined to the first and the third quadrants of the vi plane whose contour shape in general changes with both the amplitude and frequency of. Design and analysis of future memories based on switchable.
Resistive hysteretic materials change their resistance. Katiyar1 1department of physics and institute for functional nanomaterials, university of puerto rico, san juan, pr009368377, usa. Advances in resistive switching memories based on graphene oxide. Compared with an ionsbased rs, the observed rs behaviors have not shown the sharply switching feature but consecutively increasing. Resistive switching memory for nonvolatile storage and. Phasechange and redoxbased resistive switching memories. Emerging resistive switching memories jianyong ouyang. It reduces the electric potential gradient, thus negatively affecting the functionality of resistive random access memory rram devices. Resistive switching memories based on metal oxides. Advances in resistive switching based memory devices sandeep munjal and neeraj khare1. Resistive switching memory based on bioinspired natural solid polymer electrolytes.
A resistive switching memory device consisting of reduced graphene oxide and indium tin oxide as topbottom two electrodes, separated by dielectric mos2 nanosphere assemblies as. Resistive switching memories rrams are attractive for. The experimental observations show that the weibull slopes of both v reset and i reset cumulative distributions increase linearly with 1 r on. In 2012 ieee international integrated reliability workshop final report, iirw 2012.
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